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Last update: BARTOVSL/PEDF.CUNI.CZ (23.09.2008)
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Last update: BARTOVSL/PEDF.CUNI.CZ (23.09.2008)
Atkins P.W., de Paula J.: Atkins' Physical Chemistry, Oxford University Press 2006 |
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Last update: BARTOVSL/PEDF.CUNI.CZ (23.09.2008)
Solving a set of problems assigned by the lecturer |
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Last update: BARTOVSL/PEDF.CUNI.CZ (23.09.2008)
1. Basic principles and quantities of physical chemistry. State behaviour of fluids. 2.-5. Chemical thermodynamics. 1st law, internal energy, heat and work, enthalpy. Thermochemistry. 2nd law, entropy, Helmholtz and Gibbs energy. Chemical potential, criteria of equilibrium. 3rd law. 6.-7. Phase equilibria in one-component systems. Phase equilibria in multi-component systems. Vapour-liquid equilibria in ideal and real systems. Solubility of gases in liquids. Colligative properties. Three-component systems, extraction. 8.-9. Chemical equilibria. Criteria of equilibrium, equilibrium constant and its temperature dependence, standard Gibbs reaction energy 10.-11 Chemical kinetics. Rate of reaction, rate constant and its temperature dependence. Reaction order, molecularity. Mechanism of chemical reaction. Kinetic equations of simple and simultaneous homogeneous reactions. 12.-14. Electrochemistry. Equilibria in electrolyte solutions, dissociation of electrolytes, slightly soluble electrolytes. Electrolysis. Conductivity of electrolytes. Galvanic cells. |