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Course, academic year 2023/2024
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Physical Chemistry II - MC260P02
Title: Fyzikální chemie II
Guaranteed by: Department of Physical and Macromolecular Chemistry (31-260)
Faculty: Faculty of Science
Actual: from 2013
Semester: summer
E-Credits: 4
Examination process: summer s.:
Hours per week, examination: summer s.:3/0, Ex [HT]
Capacity: unlimited
Min. number of students: unlimited
4EU+: no
Virtual mobility / capacity: no
State of the course: cancelled
Language: Czech
Additional information: http://prfdec.natur.cuni.cz/~pmc/
Note: enabled for web enrollment
Guarantor: prof. RNDr. Jiří Vohlídal, CSc.
prof. RNDr. Zdeněk Samec, DrSc.
Co-requisite : MC260P01
Pre-requisite : MC260P33, MS710P04A, MS710P04B
Is pre-requisite for: MC260C11
Is interchangeable with: MC260P56
Opinion survey results   Examination dates   Schedule   
Annotation -
Second part of the basic course on Physical Chemistry, in which classification, terminology, theories and experimental methods of Electrochemistry, Chemical Kinetics, Catalysis and Colloid Chemistry are discussed.

The lecture is copmlemented by C260C02.
Last update: ZUSKOVA (01.10.2003)
Literature - Czech

J. Vohlídal, Chemická kinetika, Karolinum, Praha 2001.

Z. Samec, Elektrochemie, Karolinum, Praha 1999.

Last update: ZUSKOVA (11.02.2003)
Requirements to the exam - Czech

Zkouška je ústní. Silně akcentováno je skutečné porozumění probrané látce, nikoliv "naučení se" něčeho nazpaměť. Požadováno je též používání správné terminologie a "umění" aplikovat obecné vztahy na řešení příkladů s konkrétními látkami.

Last update: Vohlídal Jiří, prof. RNDr., CSc. (18.11.2011)
Syllabus

Basic terms and definitions, thermodynamic forces, rate of reaction, rate law, classification of reactions from the chemical kinetics point of view, reaction mechanism, steady state approximation, solutions to reaction schemes, chain reactions (linear and branched), experi-mental methods of chemical kinetics (batch and flow reactors), chemical relaxation, theory of elementary reactions (collision theory, transition state theory, calculations of steric factors) reactions in solution, cage effect, diffusion-controlled reactions, reactions controlled by chemical change (influence of the pressure, Coulombic interactions, primary salt effect, sol-vent effects), structure-to-reactivity correlations (Hammett, Taft), principles of catalysis, aci-dobasic catalysis, Hammett's acidity function, enzyme catalysis, adsorption isotherms, hetero-geneous catalysis.

Charge transport in the solid and liquid phases (electronic conductors, electrolytes, conducting polymers, electrodes, galvanic cells, membranes), coulometry, conductometry, electrochemical equilibria, electrochemical potential, theory of activity coefficients of elec-trolytes, dissociation of electrolytes, association of ions, low-soluble electrolytes, protolytic reaktions, inter-phase equilibria, Nernst potential, Donnan potential, electrode potential, elec-trode bilayer, equilibria in galvanic and voltaic cells, electrochemical kinetics, polarization of electrodes, elektrolysers, polarization methods, charge transfer kinetics (reactions involving electrons and ions), transport processes (linear diffusion, spherical diffusion, convective dif-fusion, electroosmotic flow.

Classification and basic properties of dispersion systems - Brownian motion, sedimen-tation, dialysis, electrokinetic phenomena, light scattering, supramolecular membranes.

Last update: VOHLIDAL (17.12.2002)
 
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