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Chemistry of Organoelement Compounds - MC240P20E

Title:	Chemie organoprvkových sloučenin
Guaranteed by:	Department of Inorganic Chemistry (31-240)
Faculty:	Faculty of Science
Actual:	from 2023
Semester:	summer
E-Credits:	3
Examination process:	summer s.:
Hours per week, examination:	summer s.:2/0, Ex [HT]
Capacity:	unlimited
Min. number of students:	unlimited
4EU+:	no
Virtual mobility / capacity:	no
State of the course:	cancelled
Language:	English
Note:	enabled for web enrollment

Guarantor:	prof. RNDr. Petr Štěpnička, Ph.D., DSc.
Incompatibility :	MC240C20

Opinion survey results Examination dates Schedule

Annotation -

Last update: doc. RNDr. Vojtěch Kubíček, Ph.D. (11.01.2012)

Structure, bonding, reactivity and selected applications of main group and transition metal organometallic compounds including organolanthanides and -actinides. Catalysis with participation of organometallic compounds.
The course is designed for Master and PhD students.

Literature -

Last update: doc. RNDr. Vojtěch Kubíček, Ph.D. (08.10.2013)

C. Elschenbroich: Organometallics – A concise Introduction, VCH Weinheim, any of the available editions.

Requirements to the exam -

Last update: doc. RNDr. Vojtěch Kubíček, Ph.D. (08.10.2013)

Examination is oral and follows the syllabus by covering the three main parts of the lecture, viz.

(1) organoelement chemistry of main group elements,

(2) organoelement chemistry of transition metals, lanthanides and actinides, and

(3) catalytic processes with participation of organometallic compounds.

Syllabus -

Last update: doc. RNDr. Vojtěch Kubíček, Ph.D. (08.10.2013)

Main group organoelement compounds: Groups 1, 2 and 12–16 (types, structure, synthesis and reactivity).
Carbonyls (coordination modes, structures, synthesis, reactivity).
Transition-metal organometallic compounds with η¹ – η⁸ ligands (bonding, synthesis and reactivity). Activation of C–H and C–C bonds.
Organolanthanides, organoactinides.
Isolobal relationships.
Reactions of TM-organometallic compounds (general comments).
Selected catalytic applications involving organometallic compounds.