|
|
|
||
This course offer introduction to widely-used spectroscopic and diffraction methods – i.e. electron spectroscopy (UV-VIS), vibrational spectroscopy (IR, Raman) and X-ray diffraction. Determination of the structure of selected compounds and interactions in molecular assemblies by means of molecular spectroscopies are presented and discussed. Finally issues related to the determination of solid-state structure and phase composition by the method of X-ray diffraction on crystalline materials is presented.
Last update: Němec Ivan, prof. RNDr., Ph.D. (04.02.2019)
|
|
||
Schrader B., Infrared and Raman Spectroscopy, VCH Publishers, Inc., New York 1995 Last update: Němec Ivan, prof. RNDr., Ph.D. (04.02.2019)
|
|
||
Final examination is written test, which includes all topics presented within the course. Last update: Němec Ivan, prof. RNDr., Ph.D. (22.02.2024)
|
|
||
Spectral and diffraction methods used for the structural study of compounds and supramolecular complexes - focused on instrumentation and practical applications The course is divided into the following parts: 1. Electron spectroscopy.
- Energy levels and types of transitions, potential energy curves, oscillator models, molecular parameters, selection rules - Infrared and Raman spectroscopy – basic theoretical principles, instrumentation and spectra collection - Polyatomic particles vibrations, normal vibrations, number and types of vibrations, symmetry of vibrations, character tables, representations, vibrational spectra interpretations, characteristic group vibrations - Vibrational spectroscopy of crystals, vibrational spectroscopy and allotropy and polymorphism studies
- Symmetry of molecules, symmetry operations and elements, basic postulates of the group theory, point and space symmetry groups Supporting files are available at: https://dl2.cuni.cz/course/view.php?id=5890 Last update: Němec Ivan, prof. RNDr., Ph.D. (07.02.2025)
|